Short channel effects in regioregular poly(thiophene) thin film transistors

Synthesis, characterization, and transistor response of semiconducting silole polymers with substantial hole mobility and air stability. Experiment and theory.

Realizing p-channel semiconducting polymers with good hole mobility, solution processibility, and air stability is an important step forward in the chemical manipulation of charge transport in polymeric solids and in the development of low-cost printed electronics. We report here the synthesis and full characterization of the dithienosilole- and dibenzosilole-based homopolymers, poly(4,4-di-n-h...

Short-Channel Poly-Si Thin-Film Transistors with Ultrathin Channel

Organic Thin Film Transistors Incorporating Solution Processable Thieno[3,2-b]thiophene Thienoacenes

Bottom-gate bottom-contact organic thin film transistors (OTFTs) were prepared with four novel star-shaped conjugated molecules containing a fused thieno[3,2-b]thiophene moiety incorporated either in the core and/or at the periphery of the molecular framework. The molecules were soluble in CS₂, allowing for solution-processing techniques to be employed. OTFTs with different channel geometries w...

A Comparative Study of the Gas Sensing Behavior in P3HT- and PBTTT-Based OTFTs: The Influence of Film Morphology and Contact Electrode Position

Bottom- and top-contact organic thin film transistors (OTFTs) were fabricated, using poly(3-hexylthiophene-2,5-diyl) (P3HT) and poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene] (PBTTT-C16) as p-type channel semiconductors. Four different types of OTFTs were fabricated and investigated as gas sensors against three volatile organic compounds, with different associated dipole moments...

Solution-processed single walled carbon nanotube electrodes for organic thin-film transistors

Airbrushed single walled carbon nanotube (SWCNT) thin films with sheet resistivity <1 kX/ sq. and transparency >80% are used as electrodes for pentacene and regioregular poly(3hexylthiophene) (P3HT) thin-film transistors (TFTs). Airbrushed SWCNT electrodes show low contact resistance in a bottom-contact configuration, comparable to (in the case of P3HT) or lower than (in the case of pentacene) ...